The chunk of metal sitting on a table in Joel Rosenthal’s office at the University of Delaware looks like it should belong in a wizard’s pocket. Shiny silver with shocks of pink and splashes of gold, it’s called bismuth, and it’s currently used to make products ranging from shotgun pellets to cosmetics and antacids, including Pepto-Bismol. But Professor Rosenthal’s research is expanding bismuth’s repertoire — he’s identified a kind of magic in the metal that may be just what the doctor ordered for Planet Earth. He says it could help reduce rising carbon dioxide levels in the atmosphere and provide sustainable routes to making fuels.
Rosenthal and his team in UD’s Department of Chemistry and Biochemistry have discovered that bismuth has an unusual property that can be harnessed to help the environment — as a chemical “spark” or catalyst for converting carbon dioxide (CO2), a greenhouse gas, into liquid fuels and industrial chemicals. The findings are reported in ACS Catalysis, a journal published by the American Chemical Society. Rosenthal’s team also has filed a patent on the work.
University of Delaware Professor Joel Rosenthal (right) and postdoctoral fellow Abderrahman Atifi are working on a new approach to reducing carbon dioxide emissions.
Rosenthal refers to bismuth’s specialized capability as “catalytic plasticity.” When an electrical current is applied to a bismuth film in a bath of salty liquids containing imidazolium and amidinium ions, he and his team can “tune” the chemical reaction to convert carbon dioxide to either a liquid fuel such as gasoline, or to formic acid — a valuable chemical with many industrial uses — from preserving human food and livestock feed, to manufacturing rubber and leather, artificial flavorings and perfumes.
Traditionally, chemists have needed to create a new catalyst to promote each different chemical reaction they studied, from steps a to b, from b to c, and so forth, Rosenthal said, which makes this approach — using one catalyst that can be tailored or tuned to efficiently promote multiple types of reactions — particularly novel.
“We’re working to push the boundaries of this idea,” Rosenthal said. “Our new findings are important from a technological standpoint — we think this platform will allow renewable energy sources such as solar and wind to drive the direct production of liquid fuels. But more importantly, we believe this concept of ‘catalytic plasticity’ signals a potential paradigm shift, a new way to think about renewable energy conversion, fuel production and catalysis, in general.”
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